Electrochemical treatment of wastewaters containing organic pollutants on boron-doped diamond electrodes: Prediction of specific energy consumption and required electrode area
Electrochemical treatment of wastewaters containing organic pollutants on boron-doped diamond electrodes: Prediction of specific energy consumption and required electrode area
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DOI：
10.1016/s1388-2481(01)00166-7
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发表时间：
2001-07
影响因子：
5.4
通讯作者：
M. Panizza;P. Michaud;G. Cerisola;C. Comninellis
中科院分区：
文献类型：
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作者：
M. Panizza;P. Michaud;G. Cerisola;C. Comninellis
本文对有机化合物在合成掺硼金刚石（BDD）薄膜电极上电化学燃烧的比能耗和所需电极表面进行了理论分析。该模型是制定一个完美的混合电化学反应器作为一个批量循环系统恒电流条件下。有机物的阳极氧化被认为是扩散控制下。并以苯酚的阳极氧化为例，在不同的实验条件下进行了实验验证。
A theoretical analysis is presented for the prediction of the specific energy consumption and the required electrode surface for the electrochemical combustion of organic compounds on synthetic boron-doped diamond (BDD) thin film electrodes. The model is formulated for a perfect mixed electrochemical reactor operated as a batch recirculation system under galvanostatic conditions. The anodic oxidation of organics is assumed to be under diffusion control. An experimental validation with the anodic oxidation of phenol and under different experimental conditions is also provided.