Pseudopolymorphism of an adamantane-based bisphenol containing water molecules : a role of clathrate hydrates in hydrogen-bonded networks
Pseudopolymorphism of an adamantane-based bisphenol containing water molecules : a role of clathrate hydrates in hydrogen-bonded networks
复制标题
含有水分子的金刚烷基双酚的假多晶型：笼形水合物在氢键网络中的作用
DOI：
10.1039/c1ce05253e
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发表时间：
2011
期刊：
影响因子：
--
通讯作者：
Isao Azumaya
中科院分区：
文献类型：
--
作者：
Masahide Tominaga;Hyuma Masu;Isao Azumaya
金刚烷基双酚(1)组装成三种类型的二维层，有或没有通道，或通过氢键具有笼形水合物的双重互穿的三维网络。水和水的不同化学计量量促进了不同分子堆积结构的形成。在沟渠和空腔内形成了无限的水链和有限的三角形簇。
An adamantane-based bisphenol (1) assembled into three types of 2D layers with or without channels or a doubly interpenetrated 3D network bearing clathrate hydratesviahydrogen bonds. The different stoichiometries of 1 and water facilitated the formation of the diverse molecular packing structures. Infinite chains and finite triangle clusters of water were formed within the channels and cavities.