GaCl3-assisted [2 + 3] cycloaddition: a route to tetrazaphospholes.
GaCl3-assisted [2 + 3] cycloaddition: a route to tetrazaphospholes.
复制标题
GaCl3 辅助的 [2 3] 环加成：生成四氮杂磷的途径。
作者：
A. Villinger;P. Mayer;A. Schulz
在GaCl3辅助下，Mes*-N=P-Cl （Mes* = 2,4,6- tbu3c6h2）与三甲基硅基酰化（TMS-N3）的[2 + 3]环加成形成了第一个四磷孔，该四磷孔稳定为GaCl3加合物，收率高（>96%）。
The GaCl3-assisted [2 + 3] cycloaddition of Mes*-N=P-Cl (Mes* = 2,4,6-tBu3C6H2) with trimethylsilylazide (TMS-N3) results in the formation of the first tetrazaphosphole, stabilized as a GaCl3 adduct in high yields (>96%).