A New Type of Inclusion Compounds Composed of a Charge-Transfer Complex between Tetrakis(phenylethynyl)ethene and 2,4,7-Trinitrofluorenone

A New Type of Inclusion Compounds Composed of a Charge-Transfer Complex between Tetrakis(phenylethynyl)ethene and 2,4,7-Trinitrofluorenone
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四(苯乙炔基)乙烯与2,4,7-三硝基芴酮电荷转移络合物的新型包合物

DOI:
10.1246/cl.1994.1921
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发表时间:
1994
期刊:
影响因子:
1.6
通讯作者:
T. Kitamura
T. Kitamura
中科院分区:
化学4区
文献类型:
--
作者:
Hiroshi Taniguchi;Koji Hayashi;Keiko Nishioka;Yuji Hori;Motoo Shiro;T. Kitamura

文献摘要

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四(苯乙炔基)乙烯与2,4,7-三硝基芴酮形成深红色的电荷转移络合物,与苯形成包合物。测定了苯包合物的晶体结构。该包合物由具有空穴的新型骨架组成,对苯分子具有识别作用。描述了包合化合物的其它实例。
Tetrakis(phenylethynyl)ethene and 2,4,7-trinitrofluorenone form a deep red charge-transfer complex which gives the inclusion compound with benzene. The crystal structure of the inclusion compound with benzene was determined. The inclusion compound is composed of new frameworks possessing cavities for recognition of benzene molecules. Other examples of the inclusion compound are described.