Enhanced photocurrent production from thin films of Ru(II) metallopolymer/Dawson polyoxotungstate adducts under visible irradiation.

Enhanced photocurrent production from thin films of Ru(II) metallopolymer/Dawson polyoxotungstate adducts under visible irradiation.
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DOI：
10.1039/c2cc17431f
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发表时间：
2012-03
期刊：
Chemical communications
影响因子：
4.9
通讯作者：
J. Walsh;C. Mallon;A. Bond;T. Keyes;R. Forster
J. Walsh;C. Mallon;A. Bond;T. Keyes;R. Forster
中科院分区：
化学2区
文献类型：
--
作者：
J. Walsh;C. Mallon;A. Bond;T. Keyes;R. Forster

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用Ru(II)金属聚合物敏化的多金属氧酸盐薄膜在苯甲醇和可见光存在下产生显著的光电流。值得注意的是，基于钨酸盐的加合物α-[P(2)W(18)O(62)](6-)产生的光电流大约是道森多钼酸盐α-[S(2)Mo(18)O(62)](4-)的7倍。
Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, α-[P(2)W(18)O(62)](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate α-[S(2)Mo(18)O(62)](4-).