The Thermochemical Measurements on Rubidium Compounds: A Comparison of Measured Values with Those Predicted from the NBS Tables of Chemical and Thermodynamic Properties
The Thermochemical Measurements on Rubidium Compounds: A Comparison of Measured Values with Those Predicted from the NBS Tables of Chemical and Thermodynamic Properties
复制标题
铷化合物的热化学测量：测量值与 NBS 化学和热力学性质表预测值的比较
DOI：
10.1063/1.555793
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发表时间：
1987
影响因子：
4.3
通讯作者：
R. L. Nuttall
中科院分区：
文献类型：
--
作者：
V. Parker;W. Evans;R. L. Nuttall
本报告介绍了铷化合物的热化学测量结果，这些测量结果是《NBS化学热力学性质表》中推荐的298.15 K和Δf H0（0 K）下的Δf H0、Δf G0、S0、C0p和H0（T）−H0（0）的基础。在这组热化学测量或热化学反应目录中，包括对所讨论的过程的观察值与根据上述表格中推荐的属性值预测（计算）的值的比较。评估者的最初分配的实验测量和最终估计的可靠性上的建议的过程值的不确定性。本文阐述了在准备“国家统计局化学热力学性质表”中的全套推荐数据时所使用的评估程序。
This report presents the assessed thermochemical measurements on rubidium compounds upon which the property values, Δf H0, Δf G0, S0, C0p, and H0(T)−H0(0) at 298.15 K and Δf H0(0 K) recommended in the ‘‘NBS Tables of Chemical Thermodynamic Properties’’ are based. Included in this set of thermochemical measurements, or thermochemical reaction catalog, is a comparison of the observed values for the processes in question with those predicted (calculated) from the recommended property values in the forementioned tables. The evaluator’s initially assigned uncertainties on the experimental measurements and final estimated reliabilities on the recommended process values are given. This paper illustrates the evaluation procedure used in preparing the full set of recommended data in the ‘‘NBS Tables of Chemical Thermodynamic Properties’’.