Carbon-wrapped MnO nanodendrites interspersed on reduced graphene oxide sheets as anode materials for lithium-ion batteries

Carbon-wrapped MnO nanodendrites interspersed on reduced graphene oxide sheets as anode materials for lithium-ion batteries
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碳包裹的MnO纳米枝晶散布在还原氧化石墨烯片上作为锂离子电池负极材料

DOI:
10.1016/j.apsusc.2016.10.108
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发表时间:
2017-02
影响因子:
6.7
通讯作者:
He Deyan
He Deyan
中科院分区:
材料科学1区
文献类型:
--
作者:
Liu Boli;Li Dan;Liu Zhengjiao;Gu Lili;Xie Wenhe;Li Qun;Guo Pengqian;Liu Dequan;He Deyan

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Carbon-wrapped MnO nanodendrites interspersed on reduced graphene oxide sheets (C-MnO/rGO) were prepared on nickel foam by a facile vacuum filtration and a subsequent thermal treatment. As a binder-free anode of lithium-ion battery, the nanodendritic structure of C-MnO accommodates the huge volume expansion and shortens the diffusion length for lithium ion and electron, rGO sheets prevent C-MnO nanodendites from aggregation and offer a good electronic conduction. As a result, the electrode with such a novel architecture delivers superior electrochemical properties including high reversible capacity, excellent rate capability and cycle stability. Moreover, MnO nanodendrites change to nanoparticles wrapped in graphene sheets during the lithiation/delithiation process, which is a more beneficial microstructure to further increase the specific capacity and cycle life of the electrode.
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