Proton-induced switching of the single molecule magnetic properties of a porphyrin based Tb(III) double-decker complex.
Proton-induced switching of the single molecule magnetic properties of a porphyrin based Tb(III) double-decker complex.
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DOI：
10.1039/c2cc00086e
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发表时间：
2012-07
影响因子：
4.9
通讯作者：
Daisuke Tanaka;T. Inose;Hirofumi Tanaka;Sunri Lee;N. Ishikawa;T. Ogawa
中科院分区：
文献类型：
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作者：
Daisuke Tanaka;T. Inose;Hirofumi Tanaka;Sunri Lee;N. Ishikawa;T. Ogawa
合成了一种基于四苯基卟啉的Tb（III）双层配合物，并测定了质子化和去质子化两种形式的晶体结构。交流磁化率测量表明，该双层复合物的SMM性质可以通过单个质子可逆地切换。
A tetraphenylporphyrin based Tb(III) double-decker complex has been synthesized and the crystal structure of both protonated and deprotonated forms has been determined. The ac magnetic susceptibility measurements revealed that the SMM properties of the double-decker complex can be reversibly switched by only a single proton.