Influence of silver ions on bioleaching of cobalt from spent lithium batteries

Influence of silver ions on bioleaching of cobalt from spent lithium batteries
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银离子对废旧锂电池钴生物浸出的影响

DOI:
10.1016/j.mineng.2013.04.021
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发表时间:
2013-08
影响因子:
4.8
通讯作者:
Au Chaktong
Au Chaktong
中科院分区:
工程技术2区
文献类型:
--
作者:
Zeng Guisheng;Luo Shenglian;Deng Xiaorong;Li Lei;Au Chaktong

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研究了银离子(Ag+)对氧化亚铁硫杆菌(A.研究了氧化亚铁细菌。当Ag+浓度为0.02g/L时,钴的浸出率最高,在7 d内达到98.4%,而当Ag+浓度为0.02g/L时,钴的浸出率仅为43.1%。根据SEM、XRD和EDX分析结果,推测Ag+首先与Co反应生成AgCoO 2作为中间产物。提出了一种基于催化相互作用的机理来解释使用A增强的Co浸出。氧化亚铁
The influence of silver ions (Ag+) on the bioleaching of cobalt from spent lithium batteries usingAcidithiobacillus ferrooxidans(A. ferrooxidans) bacteria was investigated. The best effect was observed at Ag+concentration of 0.02 g/L, and the amount of leached cobalt was 98.4% in a period of 7 days, whereas in the absence of Ag+, the amount of leached cobalt was only 43.1%. Based on the results of SEM, XRD and EDX investigation, it is deduced that Ag+first reacted with cobalt to form AgCoO2as an intermediate. A mechanism that is based on catalytic interactions is proposed to explain the enhanced leaching of Co usingA. ferrooxidans.
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