Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates.
Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates.
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DOI：
10.1039/c5qo00040h
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发表时间：
2015-06-01
期刊：
影响因子：
--
通讯作者：
Kalyani D
中科院分区：
文献类型：
--
作者：
Crawford JM;Shelton KE;Reeves EK;Sadarananda BK;Kalyani D
本文介绍了镍催化的苯甲酸酯直接芳基化唑的方法。全氟苯基和2-硝基苯甲酸酯参与这些反应，以中等至良好的产率得到相应的产物。用全氟苯甲酸酯芳基化的效率高度依赖于苯甲酸酯中氟原子的程度和位置。
This manuscript describes a Ni-catalyzed method for the direct arylation of azoles using benzoates. Perfluorophenyl and 2-nitrobenzoates participate in these reactions to afford the corresponding products in modest to good yields. The efficiency of the arylations with perfluorobenzoates is highly dependent on both the degree and position of fluorine atoms in the benzoates.