Intensities inΠ2−Σ2Transitions in Diatomic Molecules

Intensities inΠ2−Σ2Transitions in Diatomic Molecules
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DOI:
10.1103/physrev.48.423
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发表时间:
1935-09
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影响因子:
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通讯作者:
Lester T. Earls
Lester T. Earls
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文献类型:
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作者:
Lester T. Earls

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对于双原子分子中的Π 2− π 2和π 2− Π 2跃迁的简单强度表达式,已经通过特殊化Hill和货车Vleck给出的一般公式,在Π 2态介于Hund情况(a)和情况(B)之间的情况下得到了。在典型的1002情况下,对于J的低值,已经计算出了所有分支的数值。
Simple intensity expressions for Π 2− Σ 2 and Σ 2− Π 2 transitions in diatomic molecules have been developed for cases in which the Π 2 state is intermediate between Hund's case (a) and case (b), by specializing the general formulas given by Hill and Van Vleck. Numerical values have been worked out for all branches in typical Π 2 cases, for low values of J.