Structural isomerism in R3PSe(Ph)I compounds:: the ionic structure of [(Me2N)3PSePh]I

Structural isomerism in R3PSe(Ph)I compounds:: the ionic structure of [(Me2N)3PSePh]I
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DOI:
10.1039/b100882j
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发表时间:
2001-01-01
期刊:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
影响因子:
--
通讯作者:
Richards, CL
Richards, CL
中科院分区:
其他
文献类型:
--
作者:
Godfrey, SM;Ollerenshaw, RTA;Richards, CL

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两个摩尔当量的(Me2N)(3)P与Ph2Se2I2反应生成离子化合物[(Me2N)(3)PSePh]I,它含有一个长的Se-I接触,114.5(1)埃,和一个弯曲的P-Se-I角,3.825(2)度。
The reaction of two mole equivalents of (Me2N)(3)P with Ph2Se2I2 produces the ionic compound [(Me2N)(3)PSePh]I which contains a long Se-I contact, 3.825(1) Angstrom, and a bent P-Se-I angle, 114.5(2)degrees.