Large Electro-Optic Effect in La-Doped 0.75Pb(Mg1/3Nb2/3)O3–0.25PbTiO3 Transparent Ceramic by Two-Stage Sintering

Large Electro-Optic Effect in La-Doped 0.75Pb(Mg1/3Nb2/3)O3–0.25PbTiO3 Transparent Ceramic by Two-Stage Sintering
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DOI:
10.1111/j.1551-2916.2010.03675.x
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发表时间:
2010-08
影响因子:
3.9
通讯作者:
W. Ruan;Guorong Li;Jiangtao Zeng;J. Bian;L. Kamzina;H. Zeng;Liaoying Zheng;A. Ding
W. Ruan;Guorong Li;Jiangtao Zeng;J. Bian;L. Kamzina;H. Zeng;Liaoying Zheng;A. Ding
中科院分区:
材料科学2区
文献类型:
--
作者:
W. Ruan;Guorong Li;Jiangtao Zeng;J. Bian;L. Kamzina;H. Zeng;Liaoying Zheng;A. Ding

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以常规原料为原料,采用两段烧结法制备了掺la的0.75Pb(Mg 1/3 Nb 2/3) o3 -0.25 pbtio3高透明陶瓷。该陶瓷在红外波段的透明度高达65%。得到了较大的二次电光系数66 × 10 -16 (m/v) 2,这是迄今为止在Pb(Mg 1/3 Nb 2/3) o3 - pbtio3陶瓷中报道的最高值。研究了产生阈值电场的铁电相和透明陶瓷的畴结构。
Highly transparent ceramics of La-doped 0.75Pb(Mg 1/3 Nb 2/3 ) O 3 -0.25PbTiO 3 were fabricated by a two-stage sintering method from conventional raw materials. The ceramics exhibited a transparency as high as 65% for the infrared wavelength. Large quadratic electro-optic coefficient of 66 x 10 -16 (m/v) 2 was obtained, which was the highest value reported so far in Pb(Mg 1/3 Nb 2/3 )O 3 -PbTiO 3 ceramics. The ferroelectric phase inducing the threshold electric field E th and the domain structure of the transparent ceramics were studied.