Phosphazene base-promoted functionalization of aryltrimethylsilanes

Phosphazene base-promoted functionalization of aryltrimethylsilanes
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DOI:
10.1039/b611090h
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发表时间:
2006-01-01
影响因子:
4.9
通讯作者:
Kondo, Yoshinori
Kondo, Yoshinori
中科院分区:
化学2区
文献类型:
--
作者:
Suzawa, Koichi;Ueno, Masahiro;Kondo, Yoshinori

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采用t-Bu-P4碱的催化量研究了芳基三甲基硅烷中Ar-Si键的活化,并在芳香环上没有强吸电子基团的情况下实现了芳基三甲基硅烷的选择性官能化。
The activation of Ar-Si bonds in aryltrimethylsilane was investigated using a catalytic amount of t-Bu-P4 base and selective functionalizations of aryltrimethylsilanes in the absence of strong electron withdrawing groups on the aromatic rings were accomplished.