Synthesis of cationic oxorhenium salen complexes via μ-oxo abstraction and their activity in catalytic reductions
Synthesis of cationic oxorhenium salen complexes via μ-oxo abstraction and their activity in catalytic reductions
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DOI：
10.1021/ic0520768
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发表时间：
2006-03-20
影响因子：
4.6
通讯作者：
Abu-Omar, MM
中科院分区：
文献类型：
--
作者：
Ison, EA;Cessarich, JE;Abu-Omar, MM
通过提取氧配体与[Et3Si][B(C6F5)(4)]和[Ph3C][B(C6F5)(4)]桥联得到了阳离子氧合稀土Salen配合物。这些络合物在常温下催化2-丁酮与Et3SiH的还原反应。
Cationic oxorhenium salen complexes are prepared by the abstraction of bridging oxo ligands with [Et3Si][B(C6F5)(4)] and [Ph3C][B(C6F5)(4)]. These complexes catalyze the reduction of 2-butanone with Et3SiH under ambient conditions.