A hexanuclear iridium chain.
A hexanuclear iridium chain.
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六核铱链。
DOI:
10.1002/anie.200390152
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发表时间:
2003
影响因子:
--
通讯作者:
Luis A. Oro
中科院分区:
文献类型:
--
作者:
C. Tejel;Miguel A. Ciriano;B. Villarroya;José A. López;Fernando J. Lahoz;Luis A. Oro
Electrons in chains: A novel metallic chain made up of six iridium atoms (see picture) with an average oxidation state of +1.33 has been found in the complex HH,HT,HH-[Ir6(μ-OPy)6(I)2(CO)12] (Opy=2-pyridonate, H=head, T=tail). This complex provides a new link in the electronic sequence connecting dinuclear IrI and IrII complexes.