Photoelectrochemical cross-dehydrogenative coupling of benzothiazoles with strong aliphatic C-H bonds†
Photoelectrochemical cross-dehydrogenative coupling of benzothiazoles with strong aliphatic C-H bonds†
复制标题
DOI：
10.1039/d1cc01012c
复制
发表时间：
2021-03-24
影响因子：
4.9
通讯作者：
Ravelli, Davide
中科院分区：
文献类型：
--
作者：
Capaldo, Luca;Quadri, Lorenzo L.;Ravelli, Davide
报道了未活化的脂肪族氢供体（如烷烃）与苯并噻唑交叉偶联的光电化学策略。我们使用十聚钨酸四丁基铵作为光催化剂来激活所选基底中的强C（sp（3））-H键，而电化学则清除多余的电子。
A photoelectrochemical strategy for the cross-dehydrogenative coupling of unactivated aliphatic hydrogen donors (e.g. alkanes) with benzothiazoles is reported. We used tetrabutylammonium decatungstate as the photocatalyst to activate strong C(sp(3))-H bonds in the chosen substrates, while electrochemistry scavenged the extra electrons.