Concise preparation of fluorine-containing carbocycles involving the Diels-Alder reaction using fluorinated alkene or diene derivatives
Concise preparation of fluorine-containing carbocycles involving the Diels-Alder reaction using fluorinated alkene or diene derivatives
复制标题
使用氟化烯烃或二烯衍生物通过狄尔斯-阿尔德反应简洁制备含氟碳环
作者：
Yamada;S.; Hondo;S.; Konno;T.; Ishihara;T.
三氟乙烯基物质与各种二烯的Diels-Alder反应进行良好，以区域特异性的方式得到相应的三氟化环己烯衍生物，而2,3-二氟丁酸-1,3-二烯分子也与各种亲二烯试剂进行了顺利的Diels-Alder反应，得到相应的副二氟环己烯结构。
The Diels–Alder reaction of trifluorovinyl substances with various dienes proceeded well to give the corresponding trifluorinated cyclohexene derivatives in a regiospecific manner, while 2,3-difluorobuta-1,3-diene molecules also underwent a smooth Diels–Alder reaction with various dienophiles to afford the corresponding vic-difluorocyclohexene structure.