Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands.
Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands.
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DOI：
10.1039/c2dt12043g
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发表时间：
2012-03
影响因子：
4
通讯作者：
Ziyi Chen;Daibing Luo;Xiuchao Luo;Maoping Kang;Zhien Lin
中科院分区：
文献类型：
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作者：
Ziyi Chen;Daibing Luo;Xiuchao Luo;Maoping Kang;Zhien Lin
在溶剂热条件下合成了一种新的二维无机-有机杂化固体Cd（17）S（4）（SPh）（25）B（im）（4）（SPh =苯硫酚盐，im =咪唑盐）.结构特征为6（3）网络，17个核的镉簇通过B（im）（4）（-）配体连接。该化合物是半导体，带隙为2.66 eV，在390 nm激发下显示绿色发光。
A new two-dimensional inorganic-organic hybrid solid, formulated as Cd(17)S(4)(SPh)(25)B(im)(4) (SPh = benzenethiolate, im = imidazolate), has been synthesized under solvothermal conditions. The structure features a 6(3) network with 17-nuclear cadmium clusters linked by B(im)(4)(-) ligands. The compound is a semiconductor with the band gap of 2.66 eV and displays a green luminescence upon excitation at 390 nm.