Two Pentasilahousanes Fused Together

Two Pentasilahousanes Fused Together
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两个 Pentasilahousane 融合在一起

DOI:
10.1002/chem.201403375
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发表时间:
2014
期刊:
Chemistry - A European Journal
影响因子:
--
通讯作者:
Soichiro Kyushin
Soichiro Kyushin
中科院分区:
--
文献类型:
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作者:
Akihiro Tsurusaki;Makoto Koganezono;Kyohei Otsuka;Shintaro Ishida;Soichiro Kyushin

文献摘要

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通过1,1,3-三氯环四硅烷的还原反应合成了两个五硅杂环稠合的有机硅簇合物1。该反应涉及硅骨架的二聚和重排。通过X射线晶体学和光谱分析研究了1的结构和性质。
The organosilicon cluster1with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3‐trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of1were studied by X‐ray crystallographic and spectroscopic analyses.