Guest Responsivity of a Two-Dimensional Coordination Polymer Incorporating a Cholesterol-Based Co-Ligand
Guest Responsivity of a Two-Dimensional Coordination Polymer Incorporating a Cholesterol-Based Co-Ligand
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含有胆固醇辅助配体的二维配位聚合物的客体响应度
DOI：
10.1039/c3dt51465j
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发表时间：
2013
期刊：
影响因子：
--
通讯作者：
M. Ohba
中科院分区：
文献类型：
--
作者：
K. Kajitani;T. Koshiyama;A. Hori;R. Ohtani;A. Mishima;K. Torikai;M. Ebine;T. Oishi;M. Takata;S. Kitagawa;M. Ohba
为了实现特定的客体响应性，将疏水胆固醇基共配体胆碱-5-en-3-酰基-4-异烟酸酯（Cholpy）掺入二维霍夫曼型Co(II)Ni（II）配位聚合物中。化学编程结构成功地展示了独特的客体响应和显著的色度变化。
To implement specific guest responsivity, a hydrophobic cholesterol-based co-ligand, cholest-5-en-3-yl-4-isonicotinate (Cholpy), was incorporated into a two-dimensional Hofmann-type Co(II)Ni(II) coordination polymer. The chemically programmed structure successfully demonstrated the unique guest response with remarkable chromatic changes.