Concise Synthesis of Linderaspirone A and Bi-linderone
Concise Synthesis of Linderaspirone A and Bi-linderone
复制标题
Linderaspirone A 和 Bi-linderone 的简明合成
DOI：
10.1002/ajoc.201200184
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发表时间：
2013-03-01
影响因子：
2.7
通讯作者：
Hu, Xiangdong
中科院分区：
文献类型：
--
作者：
Xiao, Fenfen;Liu, Wu;Hu, Xiangdong
上镜：林德螺酮A的合成仅通过三个步骤完成，即达罗匹林环戊烯二酮合成和双氧辅助光化学二聚反应。 此外，还发现了林德螺酮A热异构化为联茚酮，这可能为联茚酮的生物合成途径提供线索。
Photogenic: The synthesis of linderaspirone A has been accomplished in only three steps by a Darzens cyclopentenedione synthesis and dioxygen‐assisted photochemical dimerization. Moreover, the thermal isomerization of linderaspirone A into bi‐linderone has been discovered, which may give clues to the biosynthetic pathway for bi‐linderone.