PERSISTENT ORGANIC-CHEMICALS IN SEWAGE EFFLUENTS .3. DETERMINATIONS OF NONYLPHENOXY CARBOXYLIC-ACIDS BY HIGH-RESOLUTION GAS-CHROMATOGRAPHY MASS-SPECTROMETRY AND HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
PERSISTENT ORGANIC-CHEMICALS IN SEWAGE EFFLUENTS .3. DETERMINATIONS OF NONYLPHENOXY CARBOXYLIC-ACIDS BY HIGH-RESOLUTION GAS-CHROMATOGRAPHY MASS-SPECTROMETRY AND HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
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DOI：
10.1021/es00161a011
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发表时间：
1987-07-01
影响因子：
11.4
通讯作者：
GIGER, W
中科院分区：
文献类型：
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作者：
AHEL, M;CONRAD, T;GIGER, W
在机械生物污水处理厂的进水和出水以及受污染的河流中测定了（壬基苯氧基）乙酸（NP1EC）和[（壬基苯氧基）乙氧基]乙酸（NP2EC）。通过高分辨率气相色谱/质谱 (HRGC/MS) 鉴定了一组具有不同支链壬基取代基的特征异构体。采用高效液相色谱(HPLC)和HRGC进行定量测定，相对标准偏差优于10％，检测限约为1μg/L。在二级污水中观察到高浓度的壬基苯氧基羧酸（71-330μg/L），而未经处理的污水和初级污水中的壬基苯氧基羧酸含量要低得多（
(Nonylphenoxy)acetic acid (NP1EC) and [(nonylphenoxy)ethoxy]acetic acid (NP2EC) were determined in influents and effluents of mechanical-biological sewage treatment plants and in a polluted river. A characteristic set of isomers with differently branched nonyl substituents was identified by high-resolution gas chromatography/mass spectrometry (HRGC/MS). Quantitative determinations with high-performance liquid chromatography (HPLC) and HRGC achieved relative standard deviations better than 10%, and detection limits were about 1 .mu.g/L. High concentrations of nonylphenoxy carboxylic acids were observed in secondary sewage effluents (71-330 .mu.g/L), whereas nontreated sewage and primary effluents contained much lower levels (