First Synthesis of [Fe4(η5)-C5H5)4S4](PF6)3 and Improved Syntheses of [Fe4(η5-C5H5)4S4](PF6)n (n=1,2)
First Synthesis of [Fe4(η5)-C5H5)4S4](PF6)3 and Improved Syntheses of [Fe4(η5-C5H5)4S4](PF6)n (n=1,2)
复制标题
[Fe4(η5)-C5H5)4S4](PF6)3 的首次合成和 [Fe4(η5-C5H5)4S4](PF6)n (n=1,2) 的改进合成
DOI：
10.1246/bcsj.63.2314
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发表时间：
1990
影响因子：
4
通讯作者：
M. Shimoi
中科院分区：
文献类型：
--
作者：
H. Ogino;A. Satoh;M. Shimoi
根据伏安研究结果，在所需电位下，用[Fe4(η5-C5H5)4S4]（PF6）和[Fe4(η5-C5H5)4S4](PF6)2分别以81%和82%的产率制备了[Fe4(η5-C5H5)4S4]。用+0.95 V电解[Fe4(η5-C5H5)4S4](PF6)2在乙腈中制备[Fe4(η5-C5H5)4S4](PF6)3，产率为83%。收集了[Fe4(η5-C5H5)4S4]n （n= 0,1 +, 2+, 3+）的电子光谱数据。
[Fe4(η5)-C5H5)4S4](PF6) and [Fe4(η5-C5H5)4S4](PF6)2 were prepared in 81 and 82% yields, respectively, by bulk electrolysis of [Fe4(η5-C5H5)4S4] at the requisite potentials according to the results of voltammetric studies. [Fe4(η5-C5H5)4S4](PF6)3 was prepared and isolated first by electrolysis of [Fe4(η5-C5H5)4S4](PF6)2 in acetonitrile at +0.95 V vs. SCE in 83% yield. The electronic spectral data for [Fe4(η5-C5H5)4S4]n (n=0, 1+, 2+, 3+) were collected.