Mechanistic Studies of the Formation of Zirconium Alkylidene Complexes [η5-C5H3-1,3-(SiMe2CH2PPri2)2]ZrCHR(Cl) (R = Ph, SiMe3)
Mechanistic Studies of the Formation of Zirconium Alkylidene Complexes [η5-C5H3-1,3-(SiMe2CH2PPri2)2]ZrCHR(Cl) (R = Ph, SiMe3)
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亚烷基锆配合物[η5-C5H3-1,3-(SiMe2CH2PPri2)2]ZrCHR(Cl) (R = Ph, SiMe3)形成机理研究
DOI：
10.1021/ja982969h
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发表时间：
1999
影响因子：
15
通讯作者：
L. MacGillivray
中科院分区：
文献类型：
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作者：
M. D. Fryzuk;Paul B. Duval;S. Mao;M. Zaworotko;L. MacGillivray
[P2Cp]ZrCl3(1)与2等量的KCH2Ph反应生成由[P2Cp]ZrCl2(CH2Ph)(2)、[P2Cp]ZrCl(CH2Ph)2(3)和[P2Cp]Zr(CH2Ph)3(4)组成的平衡混合烷基配合物。Th……
The reaction of [P2Cp]ZrCl3 (1) with 2 equiv of KCH2Ph generates an equilibrium mixture of alkyl complexes consisting of [P2Cp]ZrCl2(CH2Ph) (2), [P2Cp]ZrCl(CH2Ph)2 (3), and [P2Cp]Zr(CH2Ph)3 (4). Th...