Coordination and Reactivity Diversity of N-Piperidineethyl-Functionalized Indenyl Ligands: Synthesis, Structure, Theoretical Calculation, and Catalytic Activity of Organolanthanide Complexes with the Ligands

Coordination and Reactivity Diversity of N-Piperidineethyl-Functionalized Indenyl Ligands: Synthesis, Structure, Theoretical Calculation, and Catalytic Activity of Organolanthanide Complexes with the Ligands
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N-哌啶乙基官能化茚基配体的配位和反应多样性:有机镧系元素与配体配合物的合成、结构、理论计算和催化活性

DOI:
10.1021/om060979i
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发表时间:
2007-02
期刊:
影响因子:
2.8
通讯作者:
--
中科院分区:
化学2区
文献类型:
--
作者:

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研究了N-哌啶乙基取代茚化合物1-R-3-C5 H 10 NCH 2CH 2C 9 H6(R = H−(1),Me 3Si −(2))与镧系酰胺[(Me 3Si)2N]3Ln(μ-Cl)Li(THF)3(Ln = Yb,Eu,Sm,Nd)的相互作用.结果表明,配体和R
The interactions of N-piperidineethyl-functionalized indene compounds 1-R-3-C5H10NCH2CH2C9H6 (R = H− (1), Me3Si− (2)) with lanthanide(III) amides [(Me3Si)2N]3Ln(μ-Cl)Li(THF)3 (Ln = Yb, Eu, Sm, Nd) were studied. The results indicated that the ligands and r