Short- and long-term corrosion behavior of carbonate apatite-coated Mg-4mass% Y-3mass% RE alloy in cell culture medium

Short- and long-term corrosion behavior of carbonate apatite-coated Mg-4mass% Y-3mass% RE alloy in cell culture medium
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DOI:
10.1016/j.corsci.2022.110222
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发表时间:
2022-03-11
期刊:
影响因子:
8.3
通讯作者:
Akashi, Takaya
Akashi, Takaya
中科院分区:
材料科学1区
文献类型:
--
作者:
Hiromoto, Sachiko;Itoh, Sayaka;Akashi, Takaya

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在Mg-4mass% Y-3mass%稀土(WE 43)合金表面制备了不同碳酸根含量的破骨反应性碳酸磷灰石(CAp)涂层和非生物吸收性羟基磷灰石(HAp)涂层。在细胞培养基中进行电化学阻抗谱测量6小时和10周,并使用扫描电子显微镜观察腐蚀形态。CAp涂覆的样品的涂层电导率为104 Ω cm 2,高于HAp涂覆的样品的2 × 10(3)Ω cm(2)。前者最初4周的平均极化电阻为4 x 10(4)-7.5 x 10(4)Ω cm(2),高于后者的2 x 10(4)Ω cm(2)。
Osteoclast responsive carbonate apatite (CAp) coatings with different carbonate content rates and non-bioabsorbable hydroxyapatite (HAp) coating were formed on Mg-4mass% Y-3mass% rare earth (WE43) alloy. Electrochemical impedance spectroscopy measurement in a cell culture medium was performed for 6 h and 10 weeks, and the corrosion morphology was observed using a scanning electron microscope. Coating layer resis-tance of the CAp-coated specimens for 6 h was 104 omega cm2 which was higher than 2 x 10(3) omega cm(2) of the HAp-coated specimen. Mean polarization resistance for the initial 4 weeks for the former was 4 x 10(4)-7.5 x 10(4) omega cm(2) which was higher than 2 x 10(4) omega cm(2) of the latter.