Inside Back Cover: Photocatalytic Formic Acid Conversion on CdS Nanocrystals with Controllable Selectivity for H 2 or CO (Angew. Chem. Int. Ed. 33/2015)
Inside Back Cover: Photocatalytic Formic Acid Conversion on CdS Nanocrystals with Controllable Selectivity for H 2 or CO (Angew. Chem. Int. Ed. 33/2015)
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封底内页：CdS 纳米晶体上的光催化甲酸转化，对 H 2 或 CO 具有可控选择性（Angew. Chem. Int. Ed. 33/2015）
DOI：
10.1002/anie.201506236
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发表时间：
2015
期刊：
影响因子：
--
通讯作者：
Kuehnel M
中科院分区：
文献类型：
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作者：
Kuehnel M
. CdS量子点的双功能性……用于光驱动的甲酸转化为气体燃料，由E。Reisner等人的来文，第9627页及其后。根据条件和颗粒表面基团，辐照CdS纳米晶体通过甲酸或一氧化碳的脱氢产生氢气和二氧化碳，并通过脱水产生水。与类似的系统相比，氢的析出以前所未有的速率发生，并且该过程确立了甲酸作为用于一氧化碳储存的材料。
. The bifunctionality of CdS quantum dots…… for the light-driven conversion of formic acid into gaseous fuels is demonstrated by E. Reisner et al. in their Communication on page 9627 ff. Depending on the conditions and particle surface groups, irradiated CdS nanocrystals produce hydrogen and carbon dioxide through dehydrogenation of formic acid or carbon monoxide and water through dehydration. Hydrogen evolution occurs at an unprecedented rate compared to analogous systems, and this process establishes formic acid as a material for carbon monoxide storage.