{VMo9O31[RC(CH2O)3]}6−: the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

{VMo9O31[RC(CH2O)3]}6−: the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates
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{VMo9O31[RC(CH2O)3]}6â:第一类三醇配体共价修饰的Keggin型多钼酸盐

DOI:
10.1039/d0dt02506b
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发表时间:
2020
期刊:
Dalton Transaction
影响因子:
--
通讯作者:
Wu Lixin
Wu Lixin
中科院分区:
其他
文献类型:
--
作者:
Qu Di;Liu Xiaoting;Duan Fengxue;Xue Rong;Li Bao;Wu Lixin

文献摘要

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Three trivacant polyoxomolybdates were constructed, presenting the first class of triol ligand covalently-decorated Keggin-type clusters through C–O–Mo bonds. The introduction of the organic component enhanced the stability of the cluster in the solid state with the leaving of active sites at the lacunary position.