Microstructure evolution of an EB-PVD NiAl coating and its underlying single crystal superalloy substrate

Microstructure evolution of an EB-PVD NiAl coating and its underlying single crystal superalloy substrate
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EB-PVD NiAl 涂层及其底层单晶高温合金基体的微观结构演变

DOI:
10.1016/j.jallcom.2016.02.115
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发表时间:
2016-07
影响因子:
6.2
通讯作者:
Gong Shengkai
Gong Shengkai
中科院分区:
材料科学2区
文献类型:
--
作者:
Gong Xueyuan;Peng Hui;Ma Yue;Guo Hongbo;Gong Shengkai

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采用电子束物理气相沉积(EB-PVD)技术在具有(001)晶向的镍基单晶高温合金表面沉积NiAl涂层。沉积态NiAl涂层为柱状晶组织,具有(110)择优取向。研究了1100 °C下NiAl涂层与高温合金基体界面附近的组织演变行为。NiAl涂层中形成了Kirkendall空洞,表明涂层和基体中元素的扩散系数不同。在高温扩散退火过程中形成了由棒状和颗粒状拓扑密堆积(TCP)相组成的互扩散区(IDZ)和由针状TCP相组成的衬底扩散区(SDZ)。经1100 °C × 10 h扩散退火后,IDZ中形成了与涂层和基体不同取向的等轴β-NiAl晶粒。但经50 h扩散退火后,IDZ中的等轴β-NiAl相转变为与基体取向一致的γ′-Ni 3Al相。此外,在扩散退火过程中发生的基板的取向筏,筏平行于涂层/基板界面。
A NiAl coating was deposited onto a Ni-based single crystal superalloy with (001) crystal orientation by electron beam physical vapor deposition (EB-PVD). The as-deposited NiAl coating showed a columnar microstructure with (110) preferred orientation. The microstructure evolution behavior near interface between the NiAl coating and superalloy substrate at 1100 °C was investigated. Kirkendall voids were formed in the NiAl coating, indicating the different elements diffusion coefficients in the coating and substrate. Interdiffusion zone (IDZ) with rod-like and granular topological close-packed (TCP) phases and substrate diffusion zone (SDZ) with needle-like TCP phases were formed during diffusion annealing at elevated temperature. The equi-axed β-NiAl grains were developed in the IDZ after diffusion annealing at 1100 °C for 10 h, which showed different orientations from the coating and substrate. However, after 50 h diffusion annealing, the equi-axed β-NiAl phases in the IDZ were transformed into γ′-Ni3Al phases which had the same orientation as the substrate. Furthermore, oriented rafting of the substrate occurred during diffusion annealing and the rafts were parallel to the coating/substrate interface.
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