Disorder and ionic polarons in solid electrolytes

Disorder and ionic polarons in solid electrolytes
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DOI:
10.1016/0022-4596(75)90287-x
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发表时间:
1975-12
影响因子:
3.3
通讯作者:
W. Pardee;G. Mahan
W. Pardee;G. Mahan
中科院分区:
化学3区
文献类型:
--
作者:
W. Pardee;G. Mahan

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探讨了离子-离子排斥和离子-声子耦合在超离子导电中的作用。有人认为,有序-无序相变是不相关的电导率不连续性,但与较高的温度的第二阶相变已被视为在一些超离子导体和我们预测的其他。计算了比热、离子分布和电导率。
The role of ion-ion repulsion and ion-phonon coupling in superionic conduction is explored. It is argued that the order-disorder phase transition is not associated with the conductivity discontinuity, but with a higher temperature second order phase transition which has been seen in some superionic conductors and which we predict for others. The specific heat, ion distribution, and conductivity are calculated.