MOF based luminescence tuning and chemical/physical sensing
MOF based luminescence tuning and chemical/physical sensing
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DOI：
10.1016/j.micromeso.2015.03.036
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发表时间：
2015-11-01
影响因子：
5.2
通讯作者：
Feldmann, C.
中科院分区：
文献类型：
--
作者：
Mueller-Buschbaum, K.;Beuerle, F.;Feldmann, C.
金属-有机骨架（M0 F）已经成为重要的多功能杂化材料，由于大量的可用金属离子和有机连接分子构成大量的骨架结构和架构，其提供高度多样化的性质。这篇综述旨在提供一个概述，涵盖了MOFs和发光等光学性质的组合，因为它打开了一个有趣的领域，从构成配体和金属的基础上的发光调谐到快速增长的潜在传感应用的MOF发光。因此，利用化学物质与MOF框架的相互作用的依赖性的可能性可以导致发光的显著变化，这提供了用于感测和检测的优异的可观察物。(C)2015 Elsevier Inc. All rights reserved.
Metal-organic frameworks (MOFs) have been emerging as important multifunctional hybrid materials offering highly diversified properties due to an extensive number of available metal ions and organic linker molecules that constitute an extensively high number of framework structures and architectures. This review intends to give an overview covering the combination of MOFs and optical properties like luminescence as it opens an intriguing field ranging from the tuning of luminescence on the base of the constituting ligands and metals to a rapidly growing number of potential sensing applications by MOF luminescence. The possibility to utilize the dependence of an interaction of a chemical species with the MOF framework can thereby lead to significant changes in the luminescence, which provides an excellent observable used for sensing and detection. (C) 2015 Elsevier Inc. All rights reserved.