Water-soluble SG1-based alkoxyamines: A breakthrough in controlled/living free-radical polymerization in aqueous dispersed media
Water-soluble SG1-based alkoxyamines: A breakthrough in controlled/living free-radical polymerization in aqueous dispersed media
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DOI：
10.1016/j.polymer.2007.07.031
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发表时间：
2007-09-21
期刊：
影响因子：
4.6
通讯作者：
Nicolas, Julien
中科院分区：
文献类型：
--
作者：
Charleux, Bernadette;Nicolas, Julien
这篇专题文章描述了氮氧自由基介导的可控/活性自由基聚合在水分散体系中的应用，如细乳液和乳液聚合。它主要集中在无环氮氧化合物SG 1与衍生的烷氧基胺，并旨在显示新的水溶性物种的最新发展如何允许一个真正的乳液聚合过程中成功实施和嵌段共聚物直接在胶乳颗粒中创建。(c)2007爱思唯尔有限公司版权所有。
This feature article describes the application of nitroxide-mediated controlled/living free-radical polymerization in aqueous dispersed systems such as miniemulsion and emulsion polymerizations. It mainly focuses on the acyclic nitroxide SG1 with derived alkoxyamines and aims to show how the recent development of new water-soluble species has allowed a true emulsion polymerization process to be successfully implemented and block copolymers to be created directly in latex particles. (c) 2007 Elsevier Ltd. All rights reserved.