Optical rotation and atomic dimension. Experimental progress on the walden inversion
Optical rotation and atomic dimension. Experimental progress on the walden inversion
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旋光度和原子尺寸。
DOI：
10.1002/recl.19460651105
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发表时间：
1946
期刊：
影响因子：
--
通讯作者：
H. Brauns
中科院分区：
文献类型：
--
作者：
H. Brauns
作为旋光度和原子尺寸系列文章的延续，设计了一种改进的氯化、溴化和碘化方法，并将其应用于旋光甲基丙基甲醇和甲基己基甲醇。结果不仅表明本系列开始时假设的旋光度与原子尺寸之间的平行性得到了证实，而且进一步表明在理解瓦尔登反演方面取得了进展。
In continuation of the series of articles on optical rotation and atomic dimension, an improved method of chlorination, bromination an iodination has been devised and applied to optically active methylpropylcarbinol and methylhexycarbinol. The results show not only that the parallelism between optical rotation and atomic dimension, which was postulated at the beginning of this series, is confirmed, but further that progress has been made in insight into the Walden inversion.