Empirical Formulae to Molecular Structures of Metal Complexes by Molar Conductance
Empirical Formulae to Molecular Structures of Metal Complexes by Molar Conductance
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DOI：
10.1080/15533174.2012.756898
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发表时间：
2013-10-21
影响因子：
--
通讯作者：
Saleem, Kishwar
中科院分区：
文献类型：
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作者：
Ali, Imran;Wani, Waseem A.;Saleem, Kishwar
电解液的摩尔电导研究一直令化学家们感到兴奋。对金属络合物溶液的电解行为的研究提供了对其性质和组成的简要了解。这些研究提供了特定溶液中负责电流传导的离子数量的线索，从而可以获得相当重要的结构信息。利用摩尔电导数据来确定金属络合物的电解性和非电解性。人们试图总结金属络合物在不同溶剂中的摩尔电导范围，这可能被证明对研究人员和学术界有用。此外，还利用摩尔电导数据预测了金属络合物的几何构型。此外，还讨论了电导数据在估算结构相关络合物大小方面的应用。此外，还利用摩尔电导测定了金属-配体的化学计量比。最后，通过摩尔电导测量，讨论了金属络合物在不同溶剂中的结构变化。
Molar conductance studies of electrolytic solutions have always been exciting for chemists. The studies of electrolytic behavior of metal complex solutions provide brief insights into their nature and composition. These studies provide a clue of the number of ions present in a particular solution responsible for the conduction of electric current and, thereby, quite significant structural information can be obtained. Molar conductance data are exploited to ascertain electrolytic and non-electrolytic nature of metal complexes. Attempts have been made to summarize molar conductance ranges of metal complexes in various solvents, which might prove useful to researchers and academia. Besides, molar conductance data have been applied to predict geometries of metal complexes. Moreover, efforts have been made to discuss the applications of conductance data for the estimation of the size of structurally relevant complexes. In addition, molar conductance has been applied to determine metal-ligand stoichiometry. Finally, the structural variance of metal complexes in different solvents is discussed in terms of molar conductance measurements.