Effect of Local Structure of Mo Oxide on Selective Photo-Oxidation of Propane to Acetone
Effect of Local Structure of Mo Oxide on Selective Photo-Oxidation of Propane to Acetone
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DOI：
10.1007/s10562-012-0948-4
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发表时间：
2013-02
影响因子：
2.8
通讯作者：
N. Ichikuni;Y. Nakao;Kazuya Ishizuki;Takayoshi Hara;S. Shimazu
中科院分区：
文献类型：
--
作者：
N. Ichikuni;Y. Nakao;Kazuya Ishizuki;Takayoshi Hara;S. Shimazu
摘要 在氧化物载体上制备了钼氧化物，并将其应用于丙烷的选择性光氧化。介孔氧化铝上的钼氧化物具有单体结构，而介孔二氧化硅上的钼氧化物具有低聚结构。丙烷光氧化反应的主要产物分别是在氧化钼单体单元和低聚物单元上的丙酮和丙烯。 图解摘要
AbstractMo oxide species were prepared on oxide supports and applied for selective photo-oxidation of propane. Mo oxide on mesoporous alumina had a monomeric structure whereas that on mesoporous silica had an oligomeric structure. The main product of the propane photo-oxidation reaction was acetone and propene on Mo oxide monomer unit and on oligomer unit, respectively.Graphical Abstract