Asymmetric zinc porphyrin-sensitized nanosized TiO2 for efficient visible-light-driven CO2 photoreduction to CO/CH4.
Asymmetric zinc porphyrin-sensitized nanosized TiO2 for efficient visible-light-driven CO2 photoreduction to CO/CH4.
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DOI：
10.1039/c5cc03812j
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发表时间：
2015-07
影响因子：
4.9
通讯作者：
Kan Li;Li Lin;T. Peng;Yingying Guo;Renjie Li;Jing Zhang
中科院分区：
文献类型：
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作者：
Kan Li;Li Lin;T. Peng;Yingying Guo;Renjie Li;Jing Zhang
合成了不对称锌卟啉（ZnPy），并将其用于敏化纳米TiO 2。在未负载贵金属的情况下，观察到ZnPy敏化的TiO 2在可见光驱动下的气相CO2光还原生成CO/CH 4的活性，并对其机理进行了探讨.
Asymmetric zinc porphyrin (ZnPy) was synthesized and used to sensitize nanosized TiO2. The visible-light-driven activity of CO2 photoreduction to generate CO/CH4 in the gas phase was observed from the ZnPy-sensitized TiO2 without loading noble metal, and the mechanism was discussed.