Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate
Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate
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由双(亚乙二硫)四硫富瓦烯与三(草酸根)没食子酸酯和三(草酸根)铱酸酯组成的分子导体
DOI:
10.1039/d2ma00384h
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发表时间:
2022
影响因子:
5
通讯作者:
Martin Lee
中科院分区:
文献类型:
--
作者:
Blundell Toby J.;Morritt Alexander L.;Rusbridge Elizabeth K.;Quibell Luke;Oakes Jakob;Akutsu Hiroki;Nakazawa Yasuhiro;Imajo Shusaku;Kadoya Tomofumi;Yamada Jun-ichi;Coles Simon J.;Christensen Jeppe;Martin Lee
We present the synthesis, crystal structures and conducting properties of six new BEDT-TTF radical-cation salts with the tris(oxalato)gallate or -iridate anion. The use of halobenzenes gives 4 : 1 β′′ metallic or superconducting salts with tris(oxalato)gallate – fluorobenzene (PhF) or chlorobenzene (PhCl) as a guest molecule gives a metal, whilst the larger bromobenzene (PhBr) or iodobenzene (PhI) gives a superconductor. A 4 : 1 pseudo-κ semiconducting salt is obtained with benzonitrile as the guest molecule for tris(oxalato)iridate, and a novel 5 : 1 metal–insulator phase with tris(oxalato)iridate is also reported.
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影响因子:
4.9
作者:
K.Sugiyama;et al.;H. Akutsu
通讯作者:
H. Akutsu
影响因子:
3.1
作者:
Bin Zhang;Yan Zhang;Fen Liu;Yanjun Guo
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Yanjun Guo
影响因子:
3.1
作者:
T. Prokhorova;L. Zorina;S. Simonov;V. Zverev;E. Canadell;R. Shibaeva;E. Yagubskii
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E. Yagubskii
影响因子:
--
作者:
Lee Martin;S. Turner;P. Day;P. Guionneau;J. Howard;M. Uruichi;K. Yakushi
通讯作者:
K. Yakushi
影响因子:
2.7
作者:
S. Benmansour;C. Gómez‐García
通讯作者:
C. Gómez‐García