Chemical reactivities of the cation and anion of M@C82 (M = Y, La, and Ce)
Chemical reactivities of the cation and anion of M@C82 (M = Y, La, and Ce)
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DOI：
10.1021/ja043986b
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发表时间：
2005-02-23
影响因子：
15
通讯作者：
Kadish, KM
中科院分区：
文献类型：
--
作者：
Maeda, Y;Miyashita, J;Kadish, KM
M @ C-82 （M = Y， La和Ce）的化学还原和氧化分别产生了相应的阴离子和阳离子，表现出独特而有趣的化学反应。发现通过电离获得或失去电子的成功的可逆过程对于控制M @ C-82对亲核试剂和亲电试剂的稳定性和反应性是有用的。
The chemical reduction and oxidation of M @ C-82 (M = Y, La, and Ce) afford the corresponding anion and cation, respectively, which show unique and interesting chemical reactivities. It is found that the successful reversible gain or loss of electrons by ionization is useful for controlling the stability and reactivity of M @ C-82 toward both nucleophiles and electrophiles.