2-[P-(N-TERT-BUTYL-N-OXYAMINO)PHENYL]-4,4,5,5-TETRAMETHYL-4,5-DIHYDROIMIDAZOL-3-OXIDE-1-OXYL, A STABLE DIRADICAL WITH A TRIPLET GROUND-STATE
2-[P-(N-TERT-BUTYL-N-OXYAMINO)PHENYL]-4,4,5,5-TETRAMETHYL-4,5-DIHYDROIMIDAZOL-3-OXIDE-1-OXYL, A STABLE DIRADICAL WITH A TRIPLET GROUND-STATE
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DOI：
10.1002/anie.199509271
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发表时间：
1995-05-02
期刊：
影响因子：
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通讯作者：
IWAMURA, H
中科院分区：
文献类型：
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作者：
INOUE, K;IWAMURA, H
具有附加功能（例如供体/受体特性和过渡金属离子的配位能力）的稳定三线态双自由基对于通过在多个维度组装电子自旋（自由基中心）来构建分子磁体非常感兴趣。"] 除了杨的双自由基，['I 间亚苯基双（氮氧化物）s，[~] 和稳定的“Schlenk 烃”，1~~ 满足这两个条件的例子并不多。动力学稳定性和大能隙的要求
Stable triplet diradicals with additional functionalities such as donor/acceptor properties and ligating capabilities to transition metal ions are of great interest for the construction of molecular magnets by assembling electron spins (radical centers) in more than one dimension."] Except for Yang's biradical,['I meta-phenylenebis (nitr~ xide) s,[~] and the stabilized" Schlenk hydrocarb0n", 1~~ there are not very many examples that satisfy both the requirements of kinetic stability and a large energy gap