[3-(Iodo-acetamido)prop-yl]triphenyl-phospho-nium tetra-phenyl-borate.

[3-(Iodo-acetamido)prop-yl]triphenyl-phospho-nium tetra-phenyl-borate.
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[3-(碘乙酰胺基)丙基]三苯基鏻四苯基硼酸盐。

DOI:
10.1107/s160053681000142x
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发表时间:
2010-01-16
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Evans C
Evans C
中科院分区:
其他
文献类型:
--
作者:
Evans C

文献摘要

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标题化合物C23 H24 INOP+·C24 H20 B −是由3-氨基-丙基三苯基-磷酰溴化氢溴化物与对硝基-苯基碘代乙酸在203 K反应制得的。 不对称单元含有单一的阳离子和阴离子,它们在晶体中通过分子间的N-H π和反转相关的R 2 2(14)C-H-O相互作用,它们联合收割机沿c轴沿着形成阳离子和阴离子链。
The title compound, C23H24INOP+·C24H20B−, was prepared by treatment of 3-amino­propyl triphenyl­phospho­nium bromide hydrogen bromide with p-nitro­phenyl iodo­acetate at 203 K. The asymmetric unit contains a single cation and anion, which are linked in the crystal by inter­molecular N—H⋯π and inversion-related R 2 2(14) C—H⋯O inter­actions, which combine to form chains of cations and anions along the c axis.