Formation, isomerization, and cyclization reactions of hydroperoxyalkyl radicals in hexadecane autoxidation at 160-190.degree.C
Formation, isomerization, and cyclization reactions of hydroperoxyalkyl radicals in hexadecane autoxidation at 160-190.degree.C
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160-190℃十六烷自氧化过程中氢过氧烷基的形成、异构化和环化反应
DOI：
10.1021/ja00046a021
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发表时间：
1992
影响因子：
15
通讯作者：
M. Zinbo
中科院分区：
文献类型：
--
作者：
R. Jensen;S. Korcek;M. Zinbo
采用搅拌流动反应器，在160-190 ℃，氧压4 ~ 120 kPa条件下，研究了氧压对烃类液相自氧化反应的影响
Kinetic and mechanistic investigations of the effects of oxygen pressure on liquid-phase autoxidation reactions in hydrocarbons at elevated temperatures were carried out with hexadecane at 160-190 o C and at oxygen pressures from 4 to 120 kPa using a stirred-flow reactor