Solvent-soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2-Unit
Solvent-soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2-Unit
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溶剂可溶的配位聚合物，可重建捕获动力学不稳定的 [Cu(CO3)2]2 单元的环状骨架
DOI：
10.1021/ic400315g
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发表时间：
2013
影响因子：
4.6
通讯作者：
M. Kondo
中科院分区：
文献类型：
--
作者：
T. Inoue;K. Yamanishi;M. Kondo
合成了一种由Cu3+、双咪唑型配体和CO32-组成的新型二维配位聚合物。该化合物通过重结晶从甲醇/Et2O或Etoh/Et2O转变为新的具有环状骨架的五核配合物，捕获了动力学不稳定的[Cu(CO3)2]2-单元。
A new 2D coordination polymer consisting of CuIIions, bis-imidazole-type ligands, and CO32–was prepared. This compound converted to new pentanuclear complexes with cyclic frameworks, which trapped a kinetically labile [Cu(CO3)2]2–unit, by recrystallization from MeOH/Et2O or EtOH/Et2O.