Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(III) complex.
Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(III) complex.
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DOI：
10.1039/c5cc07448g
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发表时间：
2015-11
影响因子：
4.9
通讯作者：
Yukun Zhao;Junqi Lin;Yongdong Liu;B. Ma;Yong Ding;Mindong Chen
中科院分区：
文献类型：
--
作者：
Yukun Zhao;Junqi Lin;Yongdong Liu;B. Ma;Yong Ding;Mindong Chen
合成了一种单核Co配合物[Co(III)(DPK·OH)2]Cl （DPK = di（2-吡啶基）酮），并报道了其在可见光驱动水氧化中的稳定催化剂。配合物1的最佳周转数（TON）为1610，据我们所知，这是光催化水氧化的金属有机配合物中最大的TON。
A mononuclear Co complex, [Co(III)(DPK·OH)2]Cl (DPK = di(2-pyridyl)ketone), was synthesized and reported as a stable catalyst in visible light-driven water oxidation. The optimum turnover number (TON) of complex 1 is 1610, which, to the best of our knowledge, is the largest TON among metal-organic complexes for photocatalytic water oxidation.