InI3/Me3SiI-catalyzed Direct Alkylation of Enol Acetates Using Alkyl Acetates or Alkyl Ethers
InI3/Me3SiI-catalyzed Direct Alkylation of Enol Acetates Using Alkyl Acetates or Alkyl Ethers
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DOI：
10.1246/cl.2011.1223
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发表时间：
2011-11-05
影响因子：
1.6
通讯作者：
Baba, Akio
中科院分区：
文献类型：
--
作者：
Onishi, Yoshiharu;Nishimoto, Yoshihiro;Baba, Akio
用InI3和Me3SiI的组合刘易斯酸催化烯醇乙酸酯与乙酸烷基酯或烷基醚的直接偶联反应，不产生金属废料。烷基化试剂操作简便，扩大了该偶联反应的应用范围。
A combined Lewis acid of InI3 and Me3SiI was used to catalyze the direct coupling reactions of enol acetates with alkyl acetates or alkyl ethers without generating metal waste. The easily-handled alkylating reagents enlarged the application area of this coupling reaction.