Single-crystal-to-single-crystal E-->Z and Z-->E isomerizations of 3-chloroacrylic acid within the nanocavities of a supramolecular framework.
Single-crystal-to-single-crystal E-->Z and Z-->E isomerizations of 3-chloroacrylic acid within the nanocavities of a supramolecular framework.
复制标题
超分子框架纳米腔内 3-氯丙烯酸的单晶到单晶 E-->Z 和 Z-->E 异构化。
DOI：
10.1039/b703378h
复制
发表时间：
2007
影响因子：
4.9
通讯作者：
P. Coppens
中科院分区：
文献类型：
--
作者：
Shao;M. Messerschmidt;P. Coppens
3-氯丙烯酸(HClA)在超分子晶体CECR.HClA.2MeOH.1.5H(2)O(CECR=C-乙基杯[4]间苯二酚)的骨架腔内发生了单晶到单晶的光致异构化反应，晶格完全保留；随着反应的进行，观察了它们的进展。
Single-crystal-to-single-crystal E-->Z and Z-->E photo-isomerizations of 3-chloroacrylic acid (HClA) take place with full retention of the crystal lattice in the framework cavities of the supramolecular crystals CECR.HClA.2MeOH.1.5H(2)O (CECR = C-ethylcalix[4] resorcinarene); their progress has been monitored as the reaction proceeds.