The efficient synthesis of diethyl carbonate via coupling reaction from propylene oxide, CO2 and ethanol over binary PVEImBr/MgO catalyst
The efficient synthesis of diethyl carbonate via coupling reaction from propylene oxide, CO2 and ethanol over binary PVEImBr/MgO catalyst
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二元PVEImBr/MgO催化剂上环氧丙烷、CO2和乙醇偶联反应高效合成碳酸二乙酯
DOI：
10.1016/j.cattod.2016.02.052
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发表时间：
2017-03
期刊：
影响因子：
5.3
通讯作者：
Li Huiquan
中科院分区：
文献类型：
--
作者：
Wang Liguo;Ammar Muhammad;He Peng;Li Yuqian;Cao Yan;Li Fengjiao;Han Xiao;Li Huiquan
Direct synthesis of diethyl carbonate (DEC) from propylene oxide, CO2and ethanol via coupling reaction over a heterogeneous catalyst was demonstrated. In this work, a cross linked poly(ionic liquid) containing poly(1-vinyl-3-ethylimidazolium bromide)(PVEImBr) moiety was prepared via a free radical polymerization. Meanwhile, the MgO nanoplatelet with abundant basic sites was prepared, which was combined with PVEImBr to form a composite catalyst of PVEImBr/MgO. N2physisorption, TG, XRD, SEM, CO2-TPD and FT-IR were conducted to thoroughly characterize the structure and texture of the catalysts. The as-prepared heterogeneous catalyst, which simultaneously possessed the dual function of nucleophilicity and basicity, was used in the coupling reaction of propylene oxide, CO2and ethanol to synthesize diethyl carbonate and propylene glycol. The composite catalyst could promote the reaction with high efficiency, and a good catalytic performance of 54.4% diethyl carbonate yield and 59.8% propylene glycol yield could be achieved. The1H NMR and DFT calculation disclosed that greatly faster reaction rate was ascribed to the synergistic effect between the BrƟanion of PVEImBr and hydroxyl group of ethanol. Accordingly, a mechanism of the sequential reaction consisting of cycloaddition and transesterification steps was proposed.
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影响因子：
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通讯作者：
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