Two-way chromic interconversion of 2,2'-biphenol-6,6'-diyl dication with 5H,10H-dioxapyrene or 9H,10H-4,5-dihydroxyphenanthrene: Concomitant two-proton or two-electron transfer accompanied by drastic structural changes,
Two-way chromic interconversion of 2,2'-biphenol-6,6'-diyl dication with 5H,10H-dioxapyrene or 9H,10H-4,5-dihydroxyphenanthrene: Concomitant two-proton or two-electron transfer accompanied by drastic structural changes,
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2,2-联苯酚-6,6-二基二甲基与5H,10H-二氧杂芘或9H,10H-4,5-二羟基菲的双向铬互变：同时发生双质子或双电子转移，并伴有剧烈的结构
DOI：
10.1039/c5cc06338h
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发表时间：
2015
期刊：
影响因子：
--
通讯作者：
T. Suzuki
中科院分区：
文献类型：
--
作者：
Y. Sakano;R. Katoono;K. Fujiwara;T. Suzuki
标题双酚双酚的双质子或双电子转移几乎同时进行，诱导 2,6'/2',6- 或 6,6'- 键形成，分别产生二氧芘或二氢菲衍生物，并具有生动的颜色变化（卤色和电致变色）。
Two-proton or two-electron transfer of the title biphenolic dication proceeds nearly simultaneously to induce 2,6′/2′,6- or 6,6′-bond formation to give dioxapyrene or dihydrophenanthrene derivatives, respectively, with vivid changes in color (halochromism and electrochromism).