Phase Transformations in the Mixed Lithium-Magnesium Imide Li2Mg(NH)2
Phase Transformations in the Mixed Lithium-Magnesium Imide Li2Mg(NH)2
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混合亚胺锂镁 Li2Mg(NH)2 中的相变
DOI：
10.1007/s11182-019-01662-7
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发表时间：
2019
影响因子：
0.6
通讯作者：
T. I. Shaposhnikova
中科院分区：
文献类型：
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作者：
Z. Matysina;S. Zaginaichenko;D. Schur;A. Zolotarenko;A. Zolotarenko;M. T. Gabdulin;L. Kopylova;T. I. Shaposhnikova
亚胺结构-相转变的统计理论[j]。子2]Mg [(NH)]。开发了第2节，计算了亚胺[α]、[β]、[γ]三个相的自由能，并确定了它们的状态图。此外，还对等温线、等压线和等线曲线进行了分析。对于[α]和[β]相，论证了迟滞效应的可能表现。计算结果与实验数据进行了比较。
A statistical theory of structural-phase transformations in imide [Li. sub. 2] Mg [(NH). sub. 2] is developed, free energies of three phases of imide [alpha],[beta],[gamma] are calculated, and their state diagrams are determined. Also, the isotherm, isobar, and isopleth curves are examined. Possible manifestation of the hysteretic effect is demonstrated for [alpha]-and [beta]-phases. The results of calculations are compared with the experimental data.