Tandem Gold-Catalyzed HydrosilyloxylationAldol and Mannich Reaction with Alkynylaryloxysilanols in 6-exo Mode
Tandem Gold-Catalyzed HydrosilyloxylationAldol and Mannich Reaction with Alkynylaryloxysilanols in 6-exo Mode
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DOI：
10.1002/adsc.201300244
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发表时间：
2013-05-01
影响因子：
5.4
通讯作者：
Lee, Phil Ho
中科院分区：
文献类型：
--
作者：
Lee, Euichul;Ryu, Taekyu;Lee, Phil Ho
串联金催化的氢化硅氧基化醛醇和氢化硅氧基化曼尼希反应是通过在一个反应容器中以 6-exo 模式由炔基芳氧基硅烷醇原位催化生成烯醇甲硅烷基醚而开发的。
The tandem gold-catalyzed hydrosilyloxylationaldol and hydrosilyloxylationMannich reactions were developed through the formation of an enol silyl ether catalytically generated in situ from alkynylaryloxysilanols in the 6-exo mode in one reaction vessel.